In the FAQ of the Terra forum I have a couple of posts that are more "visual" rather than text and can show the "tendencies" of frequency effect.
This first link has some animated GIF's that present in a nomograph type of form a little slide show for optimizing coil/frequency selection when you have that kind of choice available.
http://www.findmall.com/read.php?55,745158,745158#msg-745158
The first table in this review of the X50 shows air tests with the X50 against a variety of targets.
The good:
1. The tests are done with the same type/size of coil at two different frequencies on the same detector, therefore more apples to apples with frequency being the dominant variable.
The bad:
1. It's in the air, and ground can skew the results, you would have to bury or mark targets in your ground to develop better data.
2. Coils can be wound with greater or less sensitivity, therefore even though the coils are the same size, one design might be wound "hotter".
http://www.findmall.com/read.php?55,290751,290751#msg-290751
And as crazyman mentions there are a whole host of other factors of individual detector designs that come into play. And perception is one of those factors. If you look at the the forums of the Minelab BBS/FBS detectors you will find that they are noted as being Silver killers. The posts of the coin/Silver finds dwarf any of the other forums. And by the way this seems to greatly agitate the U.S. based manufacturers to no end.
You will from time to time even see on those forums the complaint that the BBS/FBS detectors don't do well against low conductive targets like Nickles and Gold. Yet if you go look at the Beach & Water forum, which are the dominant(and have been for a long time) detectors for finding Gold rings? Lo & Behold the BBS/FBS based detectors rule the saltwater beaches. Are they good at finding small(fine) gold items? Apparently not as good as a more specific tool like an X-Terra with a high frequency coil, but they will certainly find gold rings without a doubt.
Keep in mind much of what I've posted has to do with "tendencies". There are very few absolutes, which is what makes the hobby interesting in figuring out what works best for what you are trying to accomplish. And yes you can spend a ton of money and time in figuring that out(Lawd knows I have)!
And I'll leave you with a vision. Picture a hunter with the latest greatest most expensive detector(we'll pick on the White's V3) at a trash filled city park. He is proudly sporting some heavy artillery and adjusting his life away as the Sun moves across the sky. Meanwhile in the same park is an Old Codger with a beat to death Tesoro Compadre he bought used for $89 that is just killing the guy with the V3. You should be a little more concerned with Bruce Lee holding a mop handle than me holding a mop handle.
HH
BarnacleBill